The first truly comprehensive account of this versatile field. Classified and well-documented, it covers:  * the chemistry of SNAr substitutions and anionic o-complexes * nucleophilic aromatic photosubstitutions * the possible role of electron transfer in some substitution processes * the ANRORC reactions  The volume also discusses for the first time the whole field of nucleophilic aromatic substitutions of hydrogen, a subject of considerable recent interest.  Researchers and students alike will appreciate the book's balanced presentation of mechanistic and synthetic features.

Nucleophilic aromatic displacement: The influence of the nitro group (Organic nitro chemistry series)

Terrier, François

VCH Publishers

This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes. Chapter 3 describes the concept of superelectrophilicity in SNAr substitutions, as it has recently emerged from the reactivity of strongly electron-deficient aromatic and heteroaromatic structures. The numerous synthetic applications are considered in depth in the chapters 4 and 5 that follow on intermolecular and intramolecular nucleophilic aromatic substitutions. Then, chapter 6 focuses on substitutions proceeding formally through displacement of a hydride ion, a hot topic in the field. The final chapter brings together concise yet comprehensive discussions surrounding SNAr photosubstitutions, radical substitutions, and ANRORC substitutions. Authored by a highly respected chemist who has contributed greatly to the field over the past two decades, this is a valuable information source for all organic chemists working in academia or the pharmaceutical and agrochemical industries.

Modern Nucleophilic Aromatic Substitution

Science & Math

Chemistry

Wiley-VCH

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Books by Terrier, François

See the best price to sell, buy, or rent books by Terrier, François. BookScouter helps to compare book prices from 25+ online bookstores and 30+ buyback vendors with a single search.

Nucleophilic aromatic displacement: The influence of the nitro group (Organic nitro chemistry series)

Modern Nucleophilic Aromatic Substitution